cis-Bis(butylamine-κN)bis[sulfadiazine(1−)-κ2 N,N′]copper(II) pentahydrate
نویسندگان
چکیده
In the title compound {systematic name: cis-bis-[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato-κ(2)N,N']bis-(butyl-amine-κN)copper(II) penta-hydrate}, [Cu(C(10)H(9)N(4)O(2)S)(2)(C(4)H(11)N)(2)]·5H(2)O or [Cu(sdz)(2)(ba)(2)]·5H(2)O [ba is butyl-amine and sdz = sulfadiazine(1-)], the copper(II) cation is six-coordinated by four N atoms of two sulfadiazine ligands and two N atoms of butyl-amine ligands. The copper(II) ion and one of the water mol-ecules lie on twofold rotation axes. One of the butyl groups is disordered over two sites, with occupancies of 0.395 (8) and 0.605 (8). The geometry around the S atom is distorted tetra-hedral. The crystal structure involves inter-molecular N-H⋯N and N-H⋯O hydrogen bonds. N-H⋯N hydrogen bonds between sdz ligands lead to a sheet structure parallel to the ab plane.
منابع مشابه
A 2:1 cocrystal of the cis and trans isomers of bis[1,1,1,5,5,5-hexafluoropentane-2,4-dionato(1−)-κ2 O,O′]bis(4-phenylpyridine N-oxide-κO)copper(II)
The title compound is a co-crystal of the cis and trans isomers, namely cis-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II)-trans-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis(4-phenyl-pyridine N-oxide-κO)copper(II) (2/1), [Cu(C(5)HF(6)O(2))(2)(C(11)H(9)NO)(2)]. In both isomers, the coordination geometry of the Cu(2+...
متن کاملBis(di-2-pyridylamine-κ2 N,N′)bis(thiocyanato-κN)nickel(II)
The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa-hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl-amine (Hdpa) ligands and two thio-cyanate anions. Both amine H atoms are involved in N-H⋯S hydrogen bonding, resulting in the formation of layers of inter-linked mol-ecules parallel to the ab plane, which are further held together by...
متن کاملBis(isocyanato-κN)bis(1,10-phenanthroline-κ2 N,N′)cobalt(II)
In the title complex, [Co(NCO)(2)(C(12)H(8)N(2))(2)], the Co(II) atom, lying on a twofold rotation axis, is coordinated in a distorted octa-hedral environment by four N atoms from two chelating phenanthroline ligands and two N atoms from two isocyanate ligands in cis positions.
متن کاملcis-Bis[(4-nitrophenyl)cyanamido-κN 1]bis(1,10-phenanthroline-κ2 N,N′)nickel(II) methanol monosolvate
In the title compound, [Ni(C(7)H(4)N(3)O(2))(2)(C(12)H(8)N(2))(2)]·CH(3)OH, the Ni(II) atom is six-coordinated in a distorted N(6) octa-hedral geometry and is chelated by two phenanthroline ligands and two phenyl-cyanamide groups which occupy cis positions. The (4-nitro-phen-yl)cyanamide anions act as monodentate ligands. There is one classical inter-molecular O-H⋯N hydrogen bond and several C-...
متن کاملBis(4,7-dichloro-1,10-phenanthroline-κ2 N,N′)bis(dicyanamido-κN)copper(II)
In the title compound, [Cu(C(2)N(3))(2)(C(12)H(6)Cl(2)N(2))(2)], the Cu(II) atom is coordinated by two chelating 4,7-dichloro-1,10-phenanthroline (4,7-Cl-phen) ligands and two dicyanamide (dca) ligands in a cis arrangement, forming a distorted octa-hedral geometry. The equatorial plane is occupied by three N atoms from two 4,7-Cl-phen ligands and one N atom from a dca ligand at shorter Cu-N dis...
متن کامل